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Volume XIV |

Analysis of nitrogen dioxide levels in the atmosphere of cities in the Moldova Region, Romania

Abstract: The novelty of this study consists in the spatio-temporal analysis of the annual, seasonal, daily and hourly concentration values of the chemical pollutant NO2 , in the 8 counties of the Moldova – Romania Region (24 stations), over a period of 14 years (2009 – 2022), in close connection with its emission sources and with the geographical factors that can amplify or diminish it. The study is representative through the temporal consistency of the data series, through their number, and by the fact that it integrates three different sub-intervals that influenced the levels of NO2: two without restrictions, in which human activity was carried out normally (2009 – 2020 and 2021 – 2022) and one pandemic (centered on 2020) in which the population’s activity was restricted. The average annual concentrations of the pollutant NO2 exceeded the limit values only at the IS-1 station (41.5 μg/m3), due to the intense road traffic on the Red Bridge, the railway traffic and the high degree of urbanization of the indicated perimeter. The effective monthly, daily and hourly average values of NO2 emissions fell within the specific quality indices of excellent, very good and good throughout the studied interval. The maximum values of the concentration of this gas (127 μg/m3 – IS-1 / 17.02.2017) were recorded in winter, due to the intensification of road traffic and the production of thermal energy for heating houses. The specific meteorological conditions (thermal inversions, fog, calm atmosphere) and the local configuration of the relief (the Bahlui valley with a depressional corridor appearance), favored the accumulation and stagnation of the pollutant, without it exceeding the limit values according to Law no. 104/15 June 2011 and without endangering the health of the population. The study provides both an overview and a detailed picture of the atmospheric distribution of NO2 in the eight counties of Moldova and can represent a reporting support for other studies to be carried out in the field of air chemistry at the base of the atmosphere.